TOPCon电池正面银浆用单分散银粉的制备

The Preparation of Monodisperse Silver Powder Used on the Front Side of TOPCon Solar Cell

  • 摘要: TOPCon电池因其高效率成为目前光伏电池的主流技术。正面银粉作为TOPCon电池的电极,直接影响电池效率,是电池的关键基础材料。TOPCon电池正面银粉要求具有较高一致性的亚微米单分散银粉。传统的单分散银粉采用分步还原法,先制备晶种再通过还原进一步生长亚微米银粉,但在生产中晶种批次稳定性难以保证。本文借鉴模板法思路,用商品化稳定的乳液产品作晶种替代经繁琐制备工艺制得的银晶种,同时借助乳液作模板,在乳液和银溶液界面还原生长亚微米银粉,以提高亚微米银粉产品的批次稳定性,简化分步还原法工艺。本文探究了乳液作晶种制备单分散亚微米银粉的可行性以及乳液作晶种对制备亚微米银粉的影响规律。结果表明,商品化乳液能够用作晶种,制备出高分散的亚微米球形银粉;乳液能够起到与银晶种类似的作用,随着乳液掺量的增加,银粉粒度变小,通过调节乳液的掺量能够调控亚微米银粉的粒度。

     

    Abstract: TOPCon solar cells have become the dominant technology of photovoltaic cells because of their high cell efficiency.As the electrode of TOPCon solar cells, silver powder on the front side directly affects the efficiency, so it is the key basic material of the cell.The front side of TOPCon cells requires submicron-sized and monodisperse silver powder with high consistency.Traditionally, monodisperse silver powder has been prepared in two steps: firstly, the silver crystal seed has been prepared, then submicron-sized silver powder has been reduced, but the stability of seed batch production is difficult to guarantee.In this paper, using the template method as a reference, a commercially stable emulsion product is used as crystal seed to replace silver crystal seed produced by a complicated preparation process.At the same time, using emulsion as a template, submicron-sized silver powder is reduced and grown at the interface of emulsion and solution to improve the batch stability of submicron-sized silver powder products and simplify the step-by-step reduction process.In this paper, the feasibility of preparing monodisperse silver powder by using emulsion product as crystal seed and the effect of emulsion product as crystal seed on submicron-sized silver powder were investigated.The results show that the commercial emulsion can be used as crystal seed to prepare highly dispersed and submicron-sized spherical silver powder.As the emulsion product playing a similar role to silver crystal seed, the particle size of silver powder decreasing with the increase of emulsion content shows that the submicron-sized particle size of silver powder can be adjusted by adjusting the emulsion content.

     

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